K. Tanoue et Y. Mukaiyama, GEOMETRICAL PROPERTIES OF BUBBLES IN P M TUNGSTEN FINE WIRES AND COMPUTER-SIMULATION ON THEIR EFFECT ON ABNORMAL GRAIN-GROWTH/, Nippon Kinzoku Gakkaishi, 61(11), 1997, pp. 1188-1197
Scanning electron microscopic (SEM) observation is made to examine the
geometry of bubbles in P/M tungsten fine wires after their secondary
recrystallization is completed. The effect of the geometrical properti
es of bubbles on abnormal grain growth is then investigated using a Mo
nte Carlo computer simulation technique. While bubbles, with the mean
diameter of 25 nm, are present at grain boundaries with a high number
density of rho = 10(13) m(-2), the number density of bubbles inside a
grain is about 5% of rho. As the specimens are annealed, rho decreases
rapidly and thereby the mean bubble diameter increases after many sma
ll bubbles form at grain boundaries. The latter is thought to be the p
rocess of bubble formation caused by the increase in the internal pres
sure of potassium gas, while the former is considered to be the coarse
ning process of large bubbles caused by the diffusion of potassium alo
ng grain boundaries from smaller to larger bubbles. Moreover, it can b
e concluded from the results of the computer simulation that the final
abnormal grain structure is very much influenced by the mutual positi
onal relation between the arrays of bubbles and the potential abnormal
grains, being indirectly influenced by the bubble intervals in an arr
ay, the growth of bubbles, the number of initial abnormal grains and s
o on.