Ff. Shi et J. Economy, ALIPHATIC AROMATIC COPOLYESTER THERMOSET ADHESIVES - SYNTHESIS AND CHARACTERIZATION/, Polymer engineering and science, 37(3), 1997, pp. 549-558
In this paper, the synthesis and characterization of a new family of a
liphatic/aromatic copolyester resins is described. This new resin is d
erived from a two component oligomeric system consisting of a mixture
of Novolac acetates and several specially designed oligomers with carb
oxylic acid end groups. In this new material, aliphatic units have bee
n incorporated into the oligomers in order to reduce the processing te
mperature. When used as an adhesive, the new resin offers good lap she
ar strength of about 14 MPa (2000 psi) at room temperature and retains
useful properties to 80 degrees C-100 degrees C. This new system prov
ides good thermal stability, environmental resistance and char yield o
f 25-40%.