We demonstrate how the noncollinear exchange coupling between the Fe l
ayers in Fe/Cr(001) superlattices is caused by a frustrated spiral mod
ulation of the Cr moments not observed in bulk. The noncollinear coupl
ing vanishes above the Neel temperature of this commensurate antiferro
magnetic Cr order. This clarifies the essential contribution of Cr ord
ering to the coupling in the regime of smallest thicknesses where no i
ncommensurate Cr spin density wave can form. For larger Cr thicknesses
we observe a predicted incommensurate to commensurate transition with
temperature.