At cryogenic temperatures magnetic properties of ferrites change signi
ficantly from their values at room temperature, which has been the mai
n regime for most device applications. Recently, microwave ferrite dev
ices with superconducting microstrip circuits have been demonstrated a
t a temperature of 77 K with virtually no electrical conduction losses
. Conventional ferrimagnetic garnet and spinel compositions, however,
are not generally optimized for low temperatures and may require chemi
cal redesign if the full potential of these devices is to be realized.
Saturation magnetizations increase according to the Brillouin-Weiss f
unction dependence that is characteristic of all ferromagnetic materia
ls. Increased magnetocrystalline anisotropy and magnetostriction can h
ave large effects on hysteresis loop squareness and coercive fields th
at are essential for stable phase shift and efficient switching. Rare-
earth impurities and other ions with short spin-lattice relaxation tim
es can cause increased microwave losses. In this article, the basic ma
gnetochemistry pertaining to ferrites will be examined for adaptation
of ferrite technology to cryogenic environments. (C) 1997 American Ins
titute of Physics.