AFFINITY OF POL(PHENYLCYANOMETHYLENEFLUORENE) AND POLY(DICYANOMETHYLENEFLUORENE) TOWARDS METALLIC CATIONS - USES OF THE NEW INTERFACES IN ELECTROCATALYSIS

Authors
RAULTBERTHELOT J ROZE C
Citation
J. Raultberthelot et C. Roze, AFFINITY OF POL(PHENYLCYANOMETHYLENEFLUORENE) AND POLY(DICYANOMETHYLENEFLUORENE) TOWARDS METALLIC CATIONS - USES OF THE NEW INTERFACES IN ELECTROCATALYSIS, Journal of electroanalytical chemistry [1992], 435(1-2), 1997, pp. 157-163
Citations number
64
Journal title
Journal of electroanalytical chemistry [1992]
ISSN journal
15726657 → ACNP
Volume
435
Issue
1-2
Year of publication
1997
Pages
157 - 163
Database
ISI
SICI code
Abstract
Anodic oxidation of 2(9H-fluoren-9-ylidene)malononitrile and 2(9H-fluo ren-9-ylidene)-2-phenylacetonitrile leads to polyfluorenylidene posses sing an affinity towards some metallic cations leading to polymer-meta l composites. The efficiency of these new interfaces is presented duri ng the anodic oxidation of hydrazine, formaldehyde, methanol, glucose and sodium azide. For this last substrate, the detection limit with ou r new polymer-metal composite is lower than 5 X 10(-5) M. (C) 1997 Els evier Science S.A.