A series of polynaphthylimides was synthesized, and the physicochemica
l and transport properties (gas permeability and diffusivity) of these
polymers were investigated, The effect of the structure of dianhydrid
e and diamine components on the properties of the resulting polymers w
as studied. It was shown that polynaphthylimides containing meta-subst
ituted phenylene rings in a diamine component are characterized by low
er gas permeability as compared to para-substituted polymers. The cond
ensed tetracyclic structure in a dianhydride component leads to the po
lymers that show higher values of permeability and diffusion coefficie
nts.