In addition to the known diffraction techniques, field-ion microscopy
with atom probe is well established for determining the long-range ord
er parameter. The site occupation probabilities of the chemical specie
s on the different sublattices may be estimated from experimental prof
iles. However, this evaluation method demands that the superstructure
planes be identified unequivocally from the data. This condition is no
t fulfilled in all cases. We propose a new analytical method for which
this condition need not be met. (C) 1997 Elsevier Science Ltd.