POLYAZACALIX[5]ARENES - SYNTHESIS AND NMR INVESTIGATIONS

Authors
GRAUBAUM H LUTZE G COSTISELLA B
Citation
H. Graubaum et al., POLYAZACALIX[5]ARENES - SYNTHESIS AND NMR INVESTIGATIONS, Journal fur praktische Chemie, Chemiker-Zeitung, 339(3), 1997, pp. 266-271
Citations number
13
Categorie Soggetti
Chemistry,"Chemistry Applied
Journal title
Journal fur praktische Chemie, Chemiker-Zeitung → ACNP
ISSN journal
09411216
Volume
339
Issue
3
Year of publication
1997
Pages
266 - 271
Database
ISI
SICI code
0941-1216(1997)339:3<266:P-SANI>2.0.ZU;2-P
Abstract
The polyazacalix[5]arenes 5a-f were easily prepared by cyclisation of cyanuric chloride derivatives 3a-d und 4a-b. These macrocycles contain two phenylene and three 1,3,5-triazine units. The derivatisation of r eactive chlorine-containing macrocycles 5 with amines, diamines and me thanol gave compounds 6a-e. The structures and conformations of these novel macrocyclic ring systems have been investigated by various NMR m ethods.