COMMENT ON A SHAPE OF EPR-SPECTRA OF SPIN-CORRELATED RADICAL PAIRS AND SEPARATE RADICALS ESCAPED GEMINATE RECOMBINATION

Authors
Citation
Km. Salikhov, COMMENT ON A SHAPE OF EPR-SPECTRA OF SPIN-CORRELATED RADICAL PAIRS AND SEPARATE RADICALS ESCAPED GEMINATE RECOMBINATION, Applied magnetic resonance, 13(3-4), 1997, pp. 415-437
Citations number
18
Journal title
ISSN journal
09379347
Volume
13
Issue
3-4
Year of publication
1997
Pages
415 - 437
Database
ISI
SICI code
0937-9347(1997)13:3-4<415:COASOE>2.0.ZU;2-B
Abstract
For model spin-correlated radical pairs (RPs) the EPR spectra are simu lated and their shape is analyzed in detail. It is demonstrated that t he widths and intensities of the EPR spectra are determined essentiall y by the rate of the singlet-triplet dephasing and the scale of the sp in-spin interactions. It is also shown that chemical exchange of the R Ps between states with different values of the exchange and the dipole -dipole interactions can produce the apparent antiphase structure line s in the EPR spectra.