Km. Salikhov, COMMENT ON A SHAPE OF EPR-SPECTRA OF SPIN-CORRELATED RADICAL PAIRS AND SEPARATE RADICALS ESCAPED GEMINATE RECOMBINATION, Applied magnetic resonance, 13(3-4), 1997, pp. 415-437
For model spin-correlated radical pairs (RPs) the EPR spectra are simu
lated and their shape is analyzed in detail. It is demonstrated that t
he widths and intensities of the EPR spectra are determined essentiall
y by the rate of the singlet-triplet dephasing and the scale of the sp
in-spin interactions. It is also shown that chemical exchange of the R
Ps between states with different values of the exchange and the dipole
-dipole interactions can produce the apparent antiphase structure line
s in the EPR spectra.