REMARKABLY COMPLEX AND UNPREDICTABLE CYCLIZATION AND REARRANGEMENT REACTIONS OF CATIONS DERIVED FROM UNSATURATED OXIRANES

Citation
Ej. Corey et Be. Roberts, REMARKABLY COMPLEX AND UNPREDICTABLE CYCLIZATION AND REARRANGEMENT REACTIONS OF CATIONS DERIVED FROM UNSATURATED OXIRANES, Tetrahedron letters, 38(52), 1997, pp. 8921-8924
Citations number
7
Journal title
ISSN journal
00404039
Volume
38
Issue
52
Year of publication
1997
Pages
8921 - 8924
Database
ISI
SICI code
0040-4039(1997)38:52<8921:RCAUCA>2.0.ZU;2-V
Abstract
Lewis-acid catalyzed reactions of unsaturated epoxides 1 and 2 afford the unprecedented products 3 and 5, respectively. Mechanistic pathways for these reactions are presented (Schemes 2 and 4) along with a more fundamental analysis. (C) 1997 Elsevier Science Ltd.