FORMATION OF NON-RACEMIC E-OLEFINS AND Z-OLEFINS BASED ON DISCRIMINATION OF ENANTIOTOPIC CARBONYL GROUPS IN ALPHA-DIKETONES BY A CHIRAL PHOSPHONATE REAGENT

Authors
TANAKA K WATANABE T OHTA Y FUJI K
Citation
K. Tanaka et al., FORMATION OF NON-RACEMIC E-OLEFINS AND Z-OLEFINS BASED ON DISCRIMINATION OF ENANTIOTOPIC CARBONYL GROUPS IN ALPHA-DIKETONES BY A CHIRAL PHOSPHONATE REAGENT, Tetrahedron letters, 38(52), 1997, pp. 8943-8946
Citations number
15
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
38
Issue
52
Year of publication
1997
Pages
8943 - 8946
Database
ISI
SICI code
0040-4039(1997)38:52<8943:FONEAZ>2.0.ZU;2-Z
Abstract
A chiral HWE reagent reacted with an alternative carbonyl group of mes o-alpha-diketones of bicyclo[2.2.1] system to give non-racemic (Z)- an d (E)-olefins, respectively. (C) 1997 Elsevier Science Ltd.