T. Chasse et al., SULFUR-MODIFIED SURFACE OF INP(001) - EVIDENCE FOR SULFUR INCORPORATION AND SURFACE OXIDATION, Applied physics A: Materials science & processing, 65(6), 1997, pp. 543-549
A photoemission study was performed in order to obtain structural and
chemical information on a sulfurized InP(001) surface by using both hi
gh-resolution SXPS/XPS and polar angle scanned photoelectron diffracti
on (XPD). Theoretical simulations of the angular distribution curves (
ADCs) were carried out on the level of single scattering cluster calcu
lations. The ADCs of the S 2p core level of sulfur on InP(001) clearly
indicate partial incorporation of the sulfur onto phosphorus lattice
sites of the bulk InP structure. Persistence of sulfidic S species aga
inst UV/ozone exposure also suggests subsurface sulfur on InP(001). Th
e sulfur-passivation may significantly reduce the amount of surface ox
idation but cannot suppress it completely.