PRUSSIAN-WHITE AS A HIGHLY-ACTIVE MOLECULAR CATALYST FOR PROTON REDUCTION

Authors
ABE T TAGUCHI F TOKITA S KANEKO M
Citation
T. Abe et al., PRUSSIAN-WHITE AS A HIGHLY-ACTIVE MOLECULAR CATALYST FOR PROTON REDUCTION, Journal of molecular catalysis. A, Chemical, 126(2-3), 1997, pp. 89-92
Citations number
12
Journal title
Journal of molecular catalysis. A, Chemical → ACNP
ISSN journal
13811169
Volume
126
Issue
2-3
Year of publication
1997
Pages
89 - 92
Database
ISI
SICI code
1381-1169(1997)126:2-3<89:PAAHMC>2.0.ZU;2-3
Abstract
Electrocatalytic H+ reduction was found with the polynuclear iron-cyan ide complex called Prussian White (PW, K4Fe4II[Fe-II(CN)(6)](3)) coate d on a Pt electrode. The PW-coated Pt produced much larger amounts of H-2 than a bare electrode even at the theoretical potential of H+/H-2. Its electrocatalytic activity exceeded the conventional Pt catalyst. (C) 1997 Elsevier Science B.V.