In the present study potentiodynamic polarisation curves were obtained
for carbon and stainless steel in contact with 3% sodium chloride aqu
eous solution saturated with air in order to evaluate the capacity of
polyaniline in the emeraldine oxidation state to protect the surface a
gainst corrosion processes. A high stability of the PAni films was obs
erved with a gain of the corrosion potential around 270 mV more positi
ve in the substrate covered with PAni than in the case without it. Cor
rosion of steel could be prevented using the conducting polymers as a
protective layer. (C) 1997 Elsevier Science Ltd.