LOCAL MODE AXIS TILTING IN H2S

Authors
CHILD MS NAUMENKO OV SMIRNOV MA BROWN LR
Citation
Ms. Child et al., LOCAL MODE AXIS TILTING IN H2S, Molecular physics, 92(5), 1997, pp. 885-893
Citations number
28
Journal title
Molecular physics → ACNP
ISSN journal
00268976
Volume
92
Issue
5
Year of publication
1997
Pages
885 - 893
Database
ISI
SICI code
0026-8976(1997)92:5<885:LMATIH>2.0.ZU;2-A
Abstract
A physically intuitive non-resonant local mode axis tilting model for the interpretation of higher overtone bands of XH2 species is outlined and illustrated by reference to the near-infrared of spectrum H2S. Qu antitative connections with the conventional normal mode resonance cou pled picture are derived and local mode based expressions for the vibr ational-rotational wavefunctions are given. Constants are reported for the (311)-(212) and (302)-(203) bands at 11 008 cm(-1) and 12 149 cm( -1), respectively.