Potassium hexafluorophosphate KPF6 has been investigated by X-ray powd
er diffraction, calorimetry and Brillouin spectroscopy. With decreasin
g temperature, the crystal shows a sequence of phases: NaCl-type cubic
-monoclinic-monoclinic with two-phase coexistence regions in between.
In the cubic phase the elastic constants have been determined. c(44) a
nd c(12) show a slight softening.