RELATION BETWEEN ELECTRONIC AND SPATIAL STRUCTURE AND SPIN-TRANSITIONPARAMETERS IN CHAIN-LIKE FE(II) COMPOUNDS

Authors
ERENBURG SB BAUSK NV LAVRENOVA LG VARNEK VA MAZALOV LN
Citation
Sb. Erenburg et al., RELATION BETWEEN ELECTRONIC AND SPATIAL STRUCTURE AND SPIN-TRANSITIONPARAMETERS IN CHAIN-LIKE FE(II) COMPOUNDS, Solid state ionics, 101, 1997, pp. 571-577
Citations number
13
Journal title
Solid state ionics → ACNP
ISSN journal
01672738
Volume
101
Year of publication
1997
Part
1
Pages
571 - 577
Database
ISI
SICI code
0167-2738(1997)101:<571:RBEASS>2.0.ZU;2-T
Abstract
EXAFS spectroscopy is used to investigate the characteristic features of the spatial and electronic structure of the polynuclear iron(II) co mplexes with 1,2,4-triazoles and various anions. The Spin transition h as been found to be accompanied by drastic changes in spatial structur e. The increase in spin transition temperature for the complexes with variable anions ClO4-, I-, Br-, BF4-, NO3- was found to correlate with changes in the Fe-N distances and changes in bond covalence determine d from the chemical shifts in Mossbauer spectra.