A POTENTIAL HARMONIC METHOD FOR THE 3-BODY COULOMB PROBLEM

Authors
Citation
Ws. Bian et Ch. Deng, A POTENTIAL HARMONIC METHOD FOR THE 3-BODY COULOMB PROBLEM, Theoretical chemistry accounts, 98(2-3), 1997, pp. 110-116
Citations number
19
ISSN journal
1432881X
Volume
98
Issue
2-3
Year of publication
1997
Pages
110 - 116
Database
ISI
SICI code
1432-881X(1997)98:2-3<110:APHMFT>2.0.ZU;2-D
Abstract
A potential harmonic method that is suitable for the three-body coulom b systems is presented. This method is applied to solve the three-body Schroedinger equations for He and e(+)e(-)e(+) directly, and the calc ulations yield very good results for the energy. For example, we obtai n a ground-state energy of -0.26181 hartrees for e(+)e(-)e(+), and -2. 90300 hartrees for He with finite nuclear mass, in good agreement with the exact values of -0.26200 hartrees and -2.90330 hartrees. Compared with the full-set calculations, the errors in the total energy for gr ound and excited states of e(+)e(-)e(+) are very small, around -0.0001 hartrees. We conclude that the present method is one of the best PH m ethods for the three-body coulomb problem.