We studied the influence of photoelectron diffraction on magnetic line
ar dichroism and spin polarization in Co and Fe 3p photoemission excit
ed by linearly polarized synchrotron radiation. We find a strong varia
tion of the magnetic linear dichroism with emission direction. The spi
n polarization related to the spin-orbit interaction varies in a simil
ar manner. This angular variation closely tracks that of the magnetic
dichroism. In contrast, the exchange-induced spin polarization (-12 2)% does not vary appreciably with emission angle. These findings sugg
est that the main cause for the observed effects is the angular moment
um character of the photoelectron wave.