Magnetic dichroism has been observed in the angular distribution of p-
core level photoemission spectra excited from crystalline ferromagnets
by unpolarized X-rays. The angular dependence of the angular and ener
gy-resolved photoemission intensity was recorded as a function of the
emission direction with respect to the crystal, revealing a strong var
iation of the magnetic dichroism with emission angle due to photoelect
ron diffraction. This variation is particularly strong around the forw
ard scattering peaks, including sign reversals close to these directio
ns. The results demonstrate that any standard X-ray photoelectron spec
troscopy apparatus possesses the potential for combined analysis of su
rface magnetic structure and geometric structure in a chemically speci
fic way.