Mr. Castell et al., ATOMIC-RESOLUTION STM OF THE NIO(001) SURFACE-STRUCTURE AND DEFECT SITES - C(2X2) PATTERNING AND EFFECTS OF COVALENT BONDING, Surface review and letters, 4(5), 1997, pp. 1003-1008
Elevated temperature STM has been used to obtain atomic resolution ima
ges of flat regions, defect sites and step edges on the (001) surface
of crystalline nickel oxide. Identification of surface lattice sites s
een in empty and filled states (nickel and oxygen sites, respectively)
is consistent with recent theoretical results according to which NiO
is a charge transfer insulator with strongly correlated electrons. It
has been found that certain surface defects lead to the formation of s
patially delocalized hole states resulting in c(2 x 2) patterning in S
TM images. The appearance of this patterning points to the presence of
a substantial covalent contribution to chemical bonding in NiO.