H. Shinohara et Jw. Hedenquist, CONSTRAINTS ON MAGMA DEGASSING BENEATH THE FAR SOUTHEAST PORPHYRY CU-AU DEPOSIT, PHILIPPINES, Journal of Petrology, 38(12), 1997, pp. 1741-1752
K-silicate alteration in the Far Southeast (FSE) porphyry Cu-Au deposi
t formed at similar to 1.4 Ma, concentric to dikes of quartz diorite p
orphyry. At similar to 2 km paleodepth the hydrothermal system consist
ed of magmatic hypersaline liquid and vapor at 550 degrees C and less
than or equal to 50 Mpa (lithostatic pressure). Advanced argillic alte
ration formed at the same time over the deposit at less than or equal
to a km paleodepth from acidic condensates of the vapor. At greater th
an or equal to 1.3 Ma, K-silicate alteration was overprinted by 350 de
grees C magmatic liquid (similar to 5 wt % of NaCl equiv.) at hydrosta
tic pressure. Sericite alteration and much of the Cu-Au mineralization
formed at this later stage. Evolution of the magmatic fluid compositi
on was simulated with a magma-chamber crystallization model. Homogeneo
us crystallization during early stage convection is assumed, whereas a
t 50 vol. % crystals the chamber becomes stagnant and crystallizes fro
m rim to core over a narrow crystallization interval. The model calcul
ation, based on a magma chamber with 2 km thickness at 6 km depth (150
MPa) and greater than or equal to 800 degrees C (saturated melt compo
sition at 30 vol. % crystals, 5 wt % H2O, 0.2 wt % Cl and delta D of -
40 parts per thousand), can reproduce the chemical and isotopic compos
itions of the early and late magmatic fluids. The most critical factor
controlling the compositional evolution of the model hydrothermal sys
tem is the transition from convective to stagnant magma-chamber crysta
llization. There is also a sharp decrease in the rate of fluid exsolut
ion associated with this transition, which can account for the thermal
collapse of the FSE porphyry system, from K-silicate to sericite alte
ration.