I. Casanova et al., AGGREGATE EXPANSIVITY DUE TO SULFIDE OXIDATION - II - PHYSICOCHEMICALMODELING OF SULFATE ATTACK, Cement and concrete research, 27(11), 1997, pp. 1627-1632
Weathering of sulfide-bearing aggregates in concrete causes the releas
e of sulfate ions that can react with cement components to yield expan
sive products. The extent of the sulfate attack of the paste is contro
lled by the composition and size of the aggregate, the kinetics of sul
fide oxidation, the composition of cement and mix proportioning of con
crete. The extent of sulfate attack has been successfully simulated us
ing a combined kinetic-thermodynamic approach. (C) 1997 Elsevier Scien
ce Ltd.