Am. Onishchenko, DIAGNOSTICS AND AUTOMATIC CALIBRATION OF INSTRUMENTS FOR CONTROL OVERTHE COMPOSITION OF SUBSTANCES, Journal of analytical chemistry, 52(12), 1997, pp. 1128-1134
Specific features of eight types of linear calibration by two measured
signals that are used for determining the concentration are described
. It is shown that the calibration characteristic must pass through th
e centers of ellipses of equal probability density of signal dispersio
n at concentrations differing for different ellipses, but kept constan
t within each ellipse. The diagnostics of the operation of a measuring
instrument is carried out by the indication of the sign and the value
of the dispersion of a pair of signals about the calibration characte
ristic. Automatic calibration is performed at regular intervals by the
grouping method using signals measured for each of three equal groups
. As a result, the measuring instrument always operates using the last
corrected automatic calibration characteristic.