HIGH-RESOLUTION SPECTROSCOPIC STUDY OF H2SE (40(-A(1) AND (40(-),0)-B-2 STRETCHING STATES - NORMAL-MODE AND LOCAL MODE ANALYSIS(),0))

Authors
ZHOU ZY WANG XG ZHOU ZP ULENIKOV ON ONOPENKO GA ZHU QS
Citation
Zy. Zhou et al., HIGH-RESOLUTION SPECTROSCOPIC STUDY OF H2SE (40(-A(1) AND (40(-),0)-B-2 STRETCHING STATES - NORMAL-MODE AND LOCAL MODE ANALYSIS(),0)), Molecular physics, 92(6), 1997, pp. 1073-1081
Citations number
26
Journal title
Molecular physics → ACNP
ISSN journal
00268976
Volume
92
Issue
6
Year of publication
1997
Pages
1073 - 1081
Database
ISI
SICI code
0026-8976(1997)92:6<1073:HSSOH(>2.0.ZU;2-3
Abstract
High resolution spectra of the coupled and degenerate (40(+), 0) A(1) and (40(-), 0) B-2 (the local mode pair) states of H2Se are reported. The vibration-rotation transitions of (H2Se)-Se-n (n = 80, 78) were as signed by using the ground state combination differences and least-squ ares fits to yield the rotational and coupling constants for the two s tretching states with degenerate band origins: v(0)(40(+), 0) = 8894.5 04 cm(-1); v(0)(40(-), 0) = 8894.504 cm(-1). Several striking local mo de limit effects and the formation of fourfold rovibrational energy cl usters are observed and discussed.