ADSORPTION OF SULFUR-DIOXIDE BY ACTIVE-CARBON TREATED BY NITRIC-ACID - I - EFFECT OF THE TREATMENT ON ADSORPTION OF SO2 AND EXTRACTABILITY OF THE ACID FORMED
A. Lisovskii et al., ADSORPTION OF SULFUR-DIOXIDE BY ACTIVE-CARBON TREATED BY NITRIC-ACID - I - EFFECT OF THE TREATMENT ON ADSORPTION OF SO2 AND EXTRACTABILITY OF THE ACID FORMED, Carbon, 35(10-11), 1997, pp. 1639-1643
The process of adsorptive-catalytic cleaning of gas from sulfur dioxid
e using active carbon, treated by concentrated nitric acid, was studie
d. After oxidative treatment the acidity of the carbon increases and t
he basicity decreases. This results in an increase of the SO2 adsorpti
on and its oxidation to SO3, and in weaker retention of the sulfuric a
cid formed. This facilitates the removal of H2SO4 by washing of the ca
rbon and allows to obtain a more concentrated acid. The efficiency of
the treated carbon is also higher in the process of SO2 removal from a
gas similar in composition to stack gases. (C) 1997 Elsevier Science
Ltd.