REACTIVITY STUDIES ON CATIONIC NON-HYDRIDIC TRIRUTHENIUM CARBONYL CLUSTERS - REACTIONS OF [RU-3(MU(3)-AMPY)(CO)(10)][BF4] WITH HYDROGEN, TRIETHYLSILANE AND TRIPHENYLSTANNANE

Authors
CABEZA JA DELRIO I RIERA V
Citation
Ja. Cabeza et al., REACTIVITY STUDIES ON CATIONIC NON-HYDRIDIC TRIRUTHENIUM CARBONYL CLUSTERS - REACTIONS OF [RU-3(MU(3)-AMPY)(CO)(10)][BF4] WITH HYDROGEN, TRIETHYLSILANE AND TRIPHENYLSTANNANE, Inorganica Chimica Acta, 268(1), 1998, pp. 131-133
Citations number
25
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Inorganica Chimica Acta → ACNP
ISSN journal
00201693
Volume
268
Issue
1
Year of publication
1998
Pages
131 - 133
Database
ISI
SICI code
0020-1693(1998)268:1<131:RSOCNT>2.0.ZU;2-Q
Abstract
The cationic cluster complex [Ru-3(mu(3)-ampy)(CO)(10)][BF4] (1) (Hamp y = 2-amino-6-methylpyridine) reacts with hydrogen at room temperature undergoing an oxidative substitution of CO to give the cationic dihyd rido derivative [Ru-3(mu-H)(2)(mu(3)-ampy)(CO)(9)][BF4]. However, unde r similar conditions, the reactions of compound 1 with triethylsilane and triphenylstannane lead to mixtures of [Ru-3(mu-H)(mu(3)-ampy)(CO)( 9)] with the corresponding [R3E][BF4] salts (R3E=Et3Si, Ph3Sn). (C) 19 98 Elsevier Science S.A.