NEW AMINOCYCLOHEXADIENE ISOMER FROM HANTZSCH PYRIDINE SYNTHESIS

Citation
D. Muceniece et al., NEW AMINOCYCLOHEXADIENE ISOMER FROM HANTZSCH PYRIDINE SYNTHESIS, Bulletin des Societes chimiques belges, 106(7-8), 1997, pp. 467-474
Citations number
17
Categorie Soggetti
Chemistry
ISSN journal
00379646
Volume
106
Issue
7-8
Year of publication
1997
Pages
467 - 474
Database
ISI
SICI code
0037-9646(1997)106:7-8<467:NAIFHP>2.0.ZU;2-X
Abstract
1-Aminocyclohexa-1,3-diene derivatives (4) under bar and <(14)under ba r> were obtained by the reaction of N-methyl aminocrotonanilides (2) u nder bar with ethyl benzylidene acetoacetate or benzylidene acetoaceto ne under Hantzsch pyridine synthesis conditio ns. Other products of ca rbocyclization - cyclohexenones (5) under bar, (6) under bar and hydro xycyclohexanone (7) under bar were also isolated from the same reactio n.