PERMETHYLATED CYCLODEXTRINS AS CHIRAL SOLVATING AGENTS FOR THE DETERMINATION OF THE ENANTIOMERIC COMPOSITION OF APOLAR SUBSTRATES BY NMR

Authors
UCCELLOBARRETTA G BALZANO F CUZZOLA A MENICAGLI R CAPORUSSO AM SALVADORI P
Citation
G. Uccellobarretta et al., PERMETHYLATED CYCLODEXTRINS AS CHIRAL SOLVATING AGENTS FOR THE DETERMINATION OF THE ENANTIOMERIC COMPOSITION OF APOLAR SUBSTRATES BY NMR, Gazzetta chimica italiana, 127(7), 1997, pp. 383-386
Citations number
32
Categorie Soggetti
Chemistry
Journal title
Gazzetta chimica italiana → ACNP
ISSN journal
00165603
Volume
127
Issue
7
Year of publication
1997
Pages
383 - 386
Database
ISI
SICI code
0016-5603(1997)127:7<383:PCACSA>2.0.ZU;2-N
Abstract
The efficiency of hexakis(2,3,6-tri-O-methyl)-alpha-cyclodextrin (TRIM EA) and heptakis(2,3,6-tri-O-methyl)-beta-cyclodextrin (TRIMEB) as CSA s for the determination by NMR of the enantiomeric composition of tris ubstituted allenes and aromatic hydrocarbons has been compared in CD3O D as solvent: their complementary use allows the analysis of a large r ange of substrates to be carried out.