T. Kiguchi et al., EFFECT OF PHASE-SEPARATION ON FERROELASTI C DOMAIN SWITCHING IN 3 MOL-PERCENT-Y2O3-ZRO2, Nippon Seramikkusu Kyokai gakujutsu ronbunshi, 105(12), 1997, pp. 1136-1140
The effect of phase separation on ferroelastic domain switching in 3 m
ol%Y2O3-ZrO2 pseudo-single crystals annealed at 1700 degrees C was exa
mined. Domain switching occurred in two steps. From TEM analysis, the
first step seemed to be the switching of t'-phase, and the second to b
e that of t-phase, The effect of phase separation is as follows. First
by, the switching amount of t'-phase decreased with decrease of the v
olume fraction, whereas that of t-phase increased with increase of the
one, Secondly, the critical stress of t'- and t-phase increased with
growth of t-phase colony, This is because that the clamping force amon
g these phases for domain switching increase, Especially the critical
stress of t-phase was strongly effected by the colony size of t-phase.