ISOTHERMAL ELECTROCHEMICAL SYSTEMS OBTAIN ED BY COUPLING IN SERIES, IN CLOSED-CIRCUIT, OF SOME INTERFACES BETWEEN 2 IMMISCIBLE ELECTROLYTICSOLUTIONS

Authors
MIHAILCIUC C BONCIOCAT N IVANOV L SPATARU T
Citation
C. Mihailciuc et al., ISOTHERMAL ELECTROCHEMICAL SYSTEMS OBTAIN ED BY COUPLING IN SERIES, IN CLOSED-CIRCUIT, OF SOME INTERFACES BETWEEN 2 IMMISCIBLE ELECTROLYTICSOLUTIONS, Revista de chimie, 48(10-11), 1997, pp. 878-883
Citations number
14
Categorie Soggetti
Engineering, Chemical",Chemistry
Journal title
Revista de chimie → ACNP
ISSN journal
00347752
Volume
48
Issue
10-11
Year of publication
1997
Pages
878 - 883
Database
ISI
SICI code
0034-7752(1997)48:10-11<878:IESOEB>2.0.ZU;2-C
Abstract
In this paper the free-energy coupling of ion transfer (and electron t ransfer) from a qualitative point of view is studied. The main role of the hydrophilicity-hidrophobicity balance of the transferable ion is emphasized. The equilibrium distribution of an ionic redox couple in a two-phase system can be controlled by using appropriate common counte rions, or indifferent electrolytes. The ''mixed potential'' behaviour of the electrical tension of an ITIES with at least two transferable i ons is considered.