Mf. Fingas, STUDIES ON THE EVAPORATION OF CRUDE-OIL AND PETROLEUM-PRODUCTS - I - THE RELATIONSHIP BETWEEN EVAPORATION RATE AND TIME, Journal of hazardous materials, 56(3), 1997, pp. 227-236
The time dependance of evaporation was studied for several crude oils
and petroleum oil products. Evaporation was determined by weight loss
measured on a balance and recorded constantly on a computer. Examinati
on of the data shows that most oil and petroleum products evaporate at
a logarithmic rate with respect to time. This is attributed to the ov
erall logarithmic appearance of many components evaporating at differe
nt linear rates. Petroleum products with fewer chemical components, su
ch as diesel fuel, evaporate at a rate which can be best modelled as a
square root of time. The particular behaviour is shown to be a result
of the number of components evaporating by experimentation with artif
icial oils consisting of 1 to 15 components. Oils with greater than 7
components evaporating at one time can be modelled with logarithmic eq
uations; those with 3 to 7 components, with square root equations. (C)
1997 Elsevier Science B.V.