Xd. Pan et Gh. Mckinley, CHARACTERISTICS OF ELECTRORHEOLOGICAL RESPONSES IN AN EMULSION SYSTEM, Journal of colloid and interface science, 195(1), 1997, pp. 101-113
The characteristics of electrorheological (ER) responses in an emulsio
n system have been examined for the first time. The emulsion system co
nsists of a chlorinated paraffin oil and a silicone oil; these two liq
uids have similar dielectric constants, but the former liquid is 1000
times more conductive than the latter liquid. The mismatch in electric
properties between the dispersed phase and the dispersing medium can
be reversed in an emulsion by inverting the phase distribution. Transi
ent ER responses in the emulsion system have been studied over a range
of shear rates following step changes (on/off) of an external de elec
tric field. The relative response strength characterizing the ER effec
t increases with the field strength and with the volume fraction of si
licone oil, but decreases with increasing shear rate imposed. The para
ffin oil-in-silicone oil emulsion exhibits a response much stronger th
an that observed in the phase-reversed silicone oil-in-paraffin oil em
ulsion. No negative ER response is detected in the silicone oil-in-par
affin oil emulsion. With an optical microscope, very different microsc
opic response characteristics are observed for the phase-reversed emul
sions under static conditions, and this can be explained according to
the leaky dielectric liquid model of Taylor. (C) 1997 Academic Press.