CRYSTALLINE COPPER PHOSPHATES - SYNTHESIS AND THERMAL-STABILITY

Authors
BAMBERGER CE SPECHT ED ANOVITZ LM
Citation
Ce. Bamberger et al., CRYSTALLINE COPPER PHOSPHATES - SYNTHESIS AND THERMAL-STABILITY, Journal of the American Ceramic Society, 80(12), 1997, pp. 3133-3138
Citations number
13
Journal title
Journal of the American Ceramic Society → ACNP
ISSN journal
00027820
Volume
80
Issue
12
Year of publication
1997
Pages
3133 - 3138
Database
ISI
SICI code
0002-7820(1997)80:12<3133:CCP-SA>2.0.ZU;2-5
Abstract
The syntheses of Cu(PO3)(2), Cu2P2O7, Cu4P2O9, Cu5P2O10, Cu-3(PO4)(2), and Cu2PO4 were accomplished by several new solid-state routes. Attem pts to synthesize CuPO3 were unsuccessful, and it is suspected that th is compound, which is reported in the literature, may not exist. The t hermal stabilities of Cu(PO3)(2), Cu2P2O7 and Cu-3(PO4)(2) were examin ed, and their decomposition was concluded to be strongly dependent on slow kinetics.