A mathematical model was developed for aqueous sample analysis by memb
rane extraction with a sorbent interface (MESI). The model used in thi
s paper includes the consideration of boundary layers which are locate
d inside and outside of the membrane, In this study, benzene, toluene,
ethylbenzene, trichloroethylene and hexane were the standard test ana
lytes, Distribution constants of these analytes between the membrane a
nd water mere measured, Some significant parameters were investigated,
such as agitation, temperature and headspace effect, Good agreement w
as found between the model and the experimental results.