EFFECTS OF SEED LAYERS ON THE CHARACTERISTICS OF (PB,LA)(ZR,TI)O-3 THIN-FILMS PREPARED BY ELECTRON-CYCLOTRON-RESONANCE PLASMA-ENHANCED CHEMICAL-VAPOR-DEPOSITION
Js. Shin et Wj. Lee, EFFECTS OF SEED LAYERS ON THE CHARACTERISTICS OF (PB,LA)(ZR,TI)O-3 THIN-FILMS PREPARED BY ELECTRON-CYCLOTRON-RESONANCE PLASMA-ENHANCED CHEMICAL-VAPOR-DEPOSITION, JPN J A P 1, 36(11), 1997, pp. 6909-6914
The effects of seed layers on the characteristics of La-doped lead zir
conate titanate (PLZT) thin films prepared by electron cyclotron reson
ance plasma enhanced chemical vapor deposition (ECR PECVD) were invest
igated. The seed layers used were lead oxide, titanate, lead titanate
and La-doped lead titanate. PLZT films with stoichiometric composition
and perovskite single phase were fabricated using titanate, lead tita
nate and La-doped lead titanate as seed layers. Among them, PLT was th
e most effective seed layer in regard to surface morphology, crystalli
nity and electrical properties of the PLZT films. The effects of seed
layers were very remarkable on the Pt/SiO2/Si substrate, however, less
significant on the Pt/Ti/SiO2/Si substrate because the Ti atoms out-d
iffused from the Ti underlayer to the substrate surface and exhibited
seed-like characteristics for the formation of perovskite phase nuclei
.