FACTORS CONTROLLING THE GENESIS OF FE-MN CRUSTS IN STRATIGRAPHIC BREAKS OF THE EASTERN BETIC CORDILLERA (SE SPAIN) DEDUCED FROM NUMERICAL-ANALYSIS OF GEOLOGICAL DATA
R. Jimenezespinosa et al., FACTORS CONTROLLING THE GENESIS OF FE-MN CRUSTS IN STRATIGRAPHIC BREAKS OF THE EASTERN BETIC CORDILLERA (SE SPAIN) DEDUCED FROM NUMERICAL-ANALYSIS OF GEOLOGICAL DATA, Sedimentary geology, 114(1-4), 1997, pp. 97-107
Fe-Mn crusts occur in four stratigraphic breaks of Jurassic pelagic sw
ell sequences in the eastern Betic Cordillera. Crusts were characteriz
ed by quantitative and qualitative variables deduced from their strati
graphic position (under-and overlying lithologies), texture (thin or b
anded), mineralogical and chemical composition. Quantitative chemical
variables were summarized in two new variables using principal compone
nt analysis. Component A groups detrital elements, and Fe with chalcop
hile elements, which suggests a seawater enrichment by detrital and hy
drothermal contributions. Component B associates elements of hydrogeno
us precipitation and adsorption during exposure of Fe-oxide to the sea
water. Relations between quantitative and qualitative variables were e
stablished by the use of correspondence analysis. Variables form two g
roups: TX1 (variables representing thin crusts, type I) and TX2 (bande
d crusts, type II). Thin crusts are related with chemical variables de
noting high detrital element contents (Al), low Mn, REE, and transitio
n metal element contents (B3), presence of detrital minerals (DET) and
Mn-Co-poor goethite (GT). Banded crusts are associated with variables
representing low detrital element contents (A2, A3), high Mn, REE, an
d transition metal element contents (B1, B2), presence of Mn-Co-rich g
oethite (MNG), Mn-oxyhydroxides (MNO), and REE-phosphates (PH). These
associations indicate that, in the type II crusts, adsorption processe
s have a greater importance than in the type I crusts. Correspondence
analysis helps to clarify the geological variables determining the ext
ent of the adsorption processes, since variables related with textural
type I are associated to lithological variables (OCL: overlying chert
y limestones; UML3: underlying thick rhythmite of marls and limestones
) indicating a geological context of pelagic swell slightly deeper tha
n those associated with the textural type II (UCC: underlying crinoida
l calcarenite; UML1: thin underlying marl-limestone rhythmite).