Energetic electrons can penetrate into the middle atmosphere causing e
xcitation, dissociation, and ionization of neutral constituents, resul
ting in chemical changes. In this paper, representative electron spect
ra measured by the Upper Atmosphere Research Satellite particle enviro
nment monitor are used to determine the relative contributions of brem
sstrahlung X rays and direct electron impact on the energy deposition
and ionization production rates for altitudes between 20 and 150 km. A
bove 50 km most of the ionization comes from direct electron impact. H
owever, in the stratosphere the energy contributed below 50 km is most
ly due to bremsstrahlung X rays. In the diffuse aurora the ionization
from the bremsstrahlung component exceeds that due to the galactic cos
mic ray background to altitudes as low as 30 km during geomagnetically
active periods. This paper demonstrates that a diffuse auroral source
can input as much or more energy into the upper portion of the lower
and middle atmosphere as previously reported for relativistic electron
events. The effects of the diffuse aurora (including both the direct
electron and the bremsstrahlung contributions) on atmospheric chemistr
y may be significant.