L. Colonescu et al., EFFECT OF ISOVALENT AND NON-ISOVALENT SUBSTITUTIONS ON SUPERCONDUCTIVITY IN NDBA2-XPRXCU3O7, Physica. C, Superconductivity, 291(1-2), 1997, pp. 85-89
We have compared for the first time the structural and superconducting
properties of (A) NdBa2-xPrxCu3O7 and (B) Nd1-uPruBa2Cu3O7. An orthor
hombic to tetragonal transition was found in A for x > 0.2 whereas for
B no such transition has been reported. In both cases superconductivi
ty was destroyed for x = 0.3 and u = 0.3 and could be restored by isov
alent Sr substitution. However, Ca substitution at the Nd site restore
d superconductivity only in the case of A. Our results indicate that d
ifferent mechanisms have to be invoked to account for the suppression
of superconductivity in compounds A and B. (C) 1997 Elsevier Science B
.V.