CHIRAL RUTHENIUM COMPLEXES AS CATALYSTS IN ENANTIOSELECTIVE DIELS-ALDER REACTIONS - CRYSTAL-STRUCTURE OF THE LEWIS-ACID DIENOPHILE ADDUCT

Authors
CARMONA D CATIVIELA C ELIPE S LAHOZ FJ LAMATA MP PILAR M DEVIU LR ORO LA VEGA C VIGURI F
Citation
D. Carmona et al., CHIRAL RUTHENIUM COMPLEXES AS CATALYSTS IN ENANTIOSELECTIVE DIELS-ALDER REACTIONS - CRYSTAL-STRUCTURE OF THE LEWIS-ACID DIENOPHILE ADDUCT, Chemical communications, (24), 1997, pp. 2351-2352
Citations number
16
Journal title
Chemical communications → ACNP
ISSN journal
13597345
Issue
24
Year of publication
1997
Pages
2351 - 2352
Database
ISI
SICI code
1359-7345(1997):24<2351:CRCACI>2.0.ZU;2-F
Abstract
On the basis of spectroscopic and structural studies a full catalytic cycle is proposed for the Diels-Alder reaction between methacrolein an d cyclopentadiene when the new chiral aquo-complexes (R-Ru, S-Ru)-[(et a(6)-p-cymene)Ru(PN)(H2O)][SbF6](2) {PN = (3aS, hosphinophenyl)-3a,8a- dihydroindane[1,2-d]oxazole} are used as catalysts.