SYNTHESIS AND STRUCTURAL CHARACTERIZATION OF TRIPODAL TITANIUM SILSESQUIOXANE COMPLEXES - A NEW CLASS OF HIGHLY-ACTIVE CATALYSTS FOR LIQUID-PHASE ALKENE EPOXIDATION

Authors
CROCKER M HEROLD RHM ORPEN AG
Citation
M. Crocker et al., SYNTHESIS AND STRUCTURAL CHARACTERIZATION OF TRIPODAL TITANIUM SILSESQUIOXANE COMPLEXES - A NEW CLASS OF HIGHLY-ACTIVE CATALYSTS FOR LIQUID-PHASE ALKENE EPOXIDATION, Chemical communications, (24), 1997, pp. 2411-2412
Citations number
11
Journal title
Chemical communications → ACNP
ISSN journal
13597345
Issue
24
Year of publication
1997
Pages
2411 - 2412
Database
ISI
SICI code
1359-7345(1997):24<2411:SASCOT>2.0.ZU;2-V
Abstract
Titanium silsesquioxane complexes [Ti(L)(R7Si7O12)], possessing tripod al geometry, represent models for heterogeneous titanosilicate catalys ts; the new complexes are exceptionally active and selective catalysts for liquid phase alkene epoxidation reactions.