Temporal variations in the atmospheric concentration of radiocarbon so
metimes result in radiocarbon-based age-estimates of biogenic material
that do not agree with true calendar age, This problem is particularl
y severe beyond the limit of the high-resolution radiocarbon calibrati
on based on tree-ring data, which stretches back only to(1,2) about 11
.8 kyr before present (BP), near the termination of the Younger Dryas
cold period If a wide range of palaeoclimate records are to be exploit
ed for better understanding the rates and patterns of environmental ch
ange during the last deglaciation, extending the well-calibrated radio
carbon timescale back further in time is crucial. Several studies atte
mpting such an extension, using uranium/thorium-dated corals(3-5) and
laminae counts in varved sediments(6-9), show conflicting results, Her
e we use radiocarbon data from varved sediments in the Cariaco basin,
in the southern Caribbean Sea, to construct an accurate and continuous
radiocarbon calibration for the period 9 to 14.5 kyr sp, nearly 3,000
years beyond the tree-ring-based calibration, A simple model compared
to the calculated atmospheric radiocarbon concentration and palaeocli
mate data from the same sediment core suggests that North Atlantic Dee
p Water formation shut down during the Younger Dryas period, but was g
radually replaced by an alternative mode of convection, possibly via t
he formation of North Atlantic Intermediate Water.