NEW REDUCED MOLYBDENUM TELLURIDES (RB,CS)(N-2)MO3NTE3N-3N CLUSTERS(2 (N = 4, 5, 6, 8) CONTAINING CONDENSED MO)

Authors
THOMAS C PICARD S GAUTIER R GOUGEON P POTEL M
Citation
C. Thomas et al., NEW REDUCED MOLYBDENUM TELLURIDES (RB,CS)(N-2)MO3NTE3N-3N CLUSTERS(2 (N = 4, 5, 6, 8) CONTAINING CONDENSED MO), Journal of alloys and compounds, 262, 1997, pp. 305-310
Citations number
9
Journal title
Journal of alloys and compounds → ACNP
ISSN journal
09258388
Volume
262
Year of publication
1997
Pages
305 - 310
Database
ISI
SICI code
0925-8388(1997)262:<305:NRMT(C>2.0.ZU;2-Z
Abstract
The syntheses, crystal growths and crystal structures of the (Rb,Cs)(n -2)Mo3nTe3n+2 (rt = 4, 5, 6, 8) compounds are reported. They crystalli ze in the space group R-3 for even n and in P6(3)/m for odd n. The Mo- Mo distances within the different Mo-3n clusters observed in the tellu rides and the analogous sulfides and selenides synthesized previously are compared. Single crystal resistivity measurements on Cs2Mo12Te14 s how a metallic behaviour in the 2-300 K temperature range. (C) 1997 El sevier Science S.A.