STRUCTURE OF Z-2-BROMO-1-FERROCENYL-1-PHENYLCYCLOPROPANES AND E-2-BROMO-1-FERROCENYL-1-PHENYLCYCLOPROPANES AND 3-FERROCENYL-3-PHENYLCYCLOPROPENE AND THEIR 3-MEMBERED RING-OPENING REACTIONS

Authors
KLIMOVA EI KLIMOVA BT RAMIREZ LR MARTINEZ GM ALVAREZ TC ESPINOSA PG TOSCANO RA
Citation
Ei. Klimova et al., STRUCTURE OF Z-2-BROMO-1-FERROCENYL-1-PHENYLCYCLOPROPANES AND E-2-BROMO-1-FERROCENYL-1-PHENYLCYCLOPROPANES AND 3-FERROCENYL-3-PHENYLCYCLOPROPENE AND THEIR 3-MEMBERED RING-OPENING REACTIONS, Journal of organometallic chemistry, 546, 1997, pp. 191-199
Citations number
18
Journal title
Journal of organometallic chemistry → ACNP
ISSN journal
0022328X
Volume
546
Year of publication
1997
Pages
191 - 199
Database
ISI
SICI code
0022-328X(1997)546:<191:SOZAE>2.0.ZU;2-Y
Abstract
The ring-opening reactions in Z- and E-2-bromo-1-ferrocenyl-1-phenylcy clopropanes and 3-ferrocenyl-3-phenylcyclopropene were studied. It was found that the three-membered ring of the monobromides is opened when treated with AlCl3, while that of cyclopropene is opened when boiled in toluene. X-ray structural data of E-2-bromo-1-ferrocenyl-1-phenylcy clopropane and 3-ferrocenyl-3-phenylcyclopropene mono crystals are pre sented. (C) 1997 Elsevier Science S.A.