SYNTHESIS, STRUCTURE OF 3-(N,N-DIMETHYLAM INO)PROPYL-DERIVATIVES AND 2-(DIMETHYLAMINOMETHYL)FERROCENYL-DERIVATIVES OF GOLD AND PLATINUM

[3-(N,N-dimethylaminopropyl]-lithium (DMAP)Li (I) reacts with chloro(t riphenylphosphane)-gold(I) ClAu . P(C6H6)(3) to form monometallic orga no gold(I)-derivate (DMAP)Au . P(C6H5)(3) (1) respectively with [2-(di methylaminomethyl)ferrocenyl]-lithium (FcN)Li (II) to form a heterobim etallic organo gold(I)-compound (FcN)Au . P(C6H5)(3) (2). Reactions of the gold(I)-complexes ClAu . P(C6H4F-p)(3), ClAu . P(C6H4F-m)(3) and ClAu . P(C6F5)(3) with II lead to the formation of (FcN)Au . P(C6H4F-p )(3) (3), (FcN)Au . P(C6H4F-m)(3) (4), respectively [FcNAu](2) (5). Th e platinum(II)-derivatives PtCl2 and cis-Cl2Pt[P(C6H5)(3)](2) react wi th II to the heterobimetallic platin organika (FcN)(2)Pt (6) and (FcN) PtCl . P(C6H5)(3) (7). A more detailed characterization of the organo derivatives 1-7 was carried out by elementary analyses, mass-, NMR-and Mossbauer spectroscopy as well as by X-ray crystal structure analyses referring to 2, 5, 6.