AN EXPERIMENTAL AND THEORETICAL-STUDY OF THE VALENCE SHELL PHOTOELECTRON-SPECTRUM OF THE BENZENE MOLECULE

The photoelectron spectrum of benzene has been studied using HeI and s ynchrotron radiation for the ionisation. The study involves all main b ands associated with the single-hole valence states, as well as satell ite structure observed in both the outer and the inner valence regions , due to many-electron effects. Many-body Green's function calculation s have been carried out employing the ADC(3) approach, and theoretical predictions for the ionisation energies and pole strengths (relative intensities) have been obtained, thus facilitating the interpretation of the experimental results. Photoelectron angular distributions and b ranching ratios have been determined using monochromated synchrotron r adiation in the photon energy range 12-120 eV. HeI excitation has been used to obtain highly resolved spectra and vibrational structure has been studied in the X E-2(1g), A E-2(2g), C E-2(1u), E B-2(1u) and F ( 2)A(1g) ionic states. In the first two bands excitations of Jahn-Telle r active modes are found to be important and very good agreement is fo und with recent theoretical studies of the vibronic structure. (C) 199 7 Elsevier Science B.V.