1,3,4-OXADIAZOLIUM-3-UNSUBSTITUTED METHANIDE 1,3-DIPOLES - USEFUL SYNTHONS AT -60-DEGREES-C - NEW SYNTHESIS OF 1,2,3-TRISUBSTITUTED AND 1,2,3,4-TETRASUBSTITUTED PYRROLES
Rn. Butler et Mo. Cloonan, 1,3,4-OXADIAZOLIUM-3-UNSUBSTITUTED METHANIDE 1,3-DIPOLES - USEFUL SYNTHONS AT -60-DEGREES-C - NEW SYNTHESIS OF 1,2,3-TRISUBSTITUTED AND 1,2,3,4-TETRASUBSTITUTED PYRROLES, Bulletin des Societes chimiques belges, 106(9-10), 1997, pp. 515-517
1,3,4-Oxadiazolium-3-unsubstituted methanides have been trapped with s
ubstituted alkyne and alkene dipolarophiles at -60 degrees C giving hi
gh yields of 2,3-di- and 2,3,4-trisubstituted 1-N-amidopyrroles from a
cycloaddition rearrangement sequence.