Jh. Clark et Dj. Macquarrie, HETEROGENEOUS CATALYSIS IN LIQUID-PHASE TRANSFORMATIONS OF IMPORTANCEIN THE INDUSTRIAL PREPARATION OF FINE CHEMICALS, Organic process research & development, 1(2), 1997, pp. 149-162
This review focuses on the use of heterogeneous catalysts in the produ
ction of fine and speciality chemicals., The major emphasis is on thos
e systems which have been commercialised already and those which are c
lose to commercialisation, These include the use of TS-1 for oxidation
reactions including the production of hydroquinone, caprolactam, and
alkene oxides, and clay-supported catalysts such as clayzic, which are
commercially available for acid-catalysed reactions, in particular Fr
iedel-Crafts reactions, Base catalysis and acid-catalysed halogenation
and nitration are also covered.