Kh. Khayat et A. Yahia, EFFECT OF WELAN GUM HIGH-RANGE WATER REDUCER COMBINATIONS ON RHEOLOGYOF CEMENT GROUT, ACI materials journal, 94(5), 1997, pp. 365-372
Polysaccharides are high-molecular weight, water-soluble organic polym
ers which can be used to reduce water dilution, bleeding, segregation,
and sedimentation in cement-based systems. Such rheology-modifying ad
mixtures increase the pseudo-plastic and thixotropic behavior of cemen
t grout and are often used in conjunction with high-range water reduce
rs that are added to compensate for some of the increase in flow resis
tance. The effects of combined additions of welan gum a commonly used
rheology modifier and naphthalene-based high-range water reducer on th
e rheological properties of cement grouts are investigated for mixture
s made with 0.40 water-to-cement ratios. Grouts with dosages of rheolo
gy-modifying admixture varying from 0 to 0.075 percent by mass of ceme
nt were prepared. For each group of grout, the concentration of high-r
ange water reducer was varied to obtain four mixtures of various fluid
ity levels. Measured properties included apparent viscosities at diffe
rent shear rates, and estimates of plastic viscosity and yield value.
Other measurements of consistency included the ease of spread and flow
of grout evaluated using the mini-slump and Marsh cone tests, respect
ively. The grout stability was evaluated by measuring its resistance t
o water dilution when cast in water as well as its ability to retain w
ater when subjected to sustained pressure (forced bleeding). Initial s
etting times were determined for selected mixtures. In all, a total of
27 grout mixtures were evaluated. Test results show that the increase
in the dosage of rheology-modifying admixture increases significantly
the yield value and plastic and apparent viscosities of cement grouts
. Combined with an adequate dosage of high-range water reducer losses
in fluidity are regained without significant reduction in stability Wi
th the increase in high-range water reducer dosage, the apparent visco
sity at low rates of shear decreases more dramatically than that at hi
gh rates of shear due to the pseudo-plastic behavior of such grouts. T
he combined use of proper dosages of theology-modifying admixture and
high-range water reducer is shown to clearly contribute to securing hi
gh-performance cement grout that is highly fluid, yet cohesive enough
to reduce water dilution and enhance water retention. For equal fluidi
ty level greater stability is obtained with mixtures containing high c
ontents of viscosity modifying admixture. The initial setting time is
shown to be delayed by the incorporation of high-range water reducer a
nd rheology-modifying admixture with the latter additive exhibiting a
greater influence on retardation of setting.