DYNAMICS AND INSTABILITIES NEAR THE GLASS-TRANSITION - FROM CLUSTERS TO CRYSTALS

Molecular dynamics simulation has been used to explore the evolution, kinetics. and dynamics of a liquid-glass transition in clusters and bu lk matter. We demonstrate a dynamical indicator that characterizes the onset of the glass transition in clusters and is consistent with othe r indicators of glass transitions in bulk systems. This criterion, bas ed on changes in chaotic behavior as measured by the largest Liapunov exponent, reveals aspects of the microscopic processes associated with the phase change from liquid to glass, and provides a connection betw een the thermodynamic and dynamical behavior of systems and their mult idimensional potential surfaces. (C) 1998 American Institute of Physic s.